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Alkane oxidation by an iron complex-hydrogen peroxide system in acetonitrile. The model of methanemonooxygenase

✍ Scribed by A. M. Khenkin; V. S. Belova; A. E. Shilov

Book ID
112399955
Publisher
Springer US
Year
1990
Tongue
English
Weight
239 KB
Volume
5
Category
Article
ISSN
1011-372X

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Oxidations by the system “hydrogen peroxide - manganese(IV) complex - acetic acid” — Part II. Hydroperoxidation and hydroxylation of alkanes in acetonitrile
✍ Georgiy B Shul'pin; Georg Süss-Fink; John R Lindsay Smith 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 694 KB

Higher alkanes (cyclohexane, n-pentane, n-heptane, methylbutane, 2-and 3methylpentanes, 3-methylhexane, cis-and trans-deealins) are oxidized at 20 °C by H202 in air in acetonitrile (or nitromethane) solution in the presence of the manganese(IV) salt [L2Mn203](PF6)2 (L = 1,4,7-trimethyl-1,4-7-triazac