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Oxidations by the system “hydrogen peroxide–manganese(IV) complex–carboxylic acid”: Part 3. Oxygenation of ethane, higher alkanes, alcohols, olefins and sulfides

✍ Scribed by Georgiy B. Shul’pin; Georg Süss-Fink; Lidia S. Shul’pina


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
318 KB
Volume
170
Category
Article
ISSN
1381-1169

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Oxidations by the system “hydrogen perox
✍ Georgiy B Shul'pin; Georg Süss-Fink; John R Lindsay Smith 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 694 KB

Higher alkanes (cyclohexane, n-pentane, n-heptane, methylbutane, 2-and 3methylpentanes, 3-methylhexane, cis-and trans-deealins) are oxidized at 20 °C by H202 in air in acetonitrile (or nitromethane) solution in the presence of the manganese(IV) salt [L2Mn203](PF6)2 (L = 1,4,7-trimethyl-1,4-7-triazac