Alkaloids from the Leaves and Stems of Daphniphyllum calycinum
✍ Scribed by Zha-Jun Zhan; Gui-Wei Rao; Xiao-Rong Hou; Cheng-Ping Li; Wei-Guang Shan
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- German
- Weight
- 182 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
One new alkaloid, named caldaphnidine H (1), together with eight known ones, daphnioldhanin G (2a), methyl homosecodaphniphyllate (3), daphnezomine M (4), daphniyunine A (5), calyciphylline A (6), deoxycalyciphylline B (7), deoxyisocalyciphylline B (8), and calyciphylline B (9) was isolated from the leaves and stems of Daphniphyllum calycinum. The structure of 1 was established by spectral methods, especially 2D‐NMR techniques. The structure of daphnioldhanin G (2b) reported previously was revised to 2a mainly by single‐crystal X‐ray diffraction and spectral analysis.
📜 SIMILAR VOLUMES
Two new Daphniphyllum alkaloids, 9,10-epoxycalycinine A (1) and homodaphniphyllate (2), together with eight known related alkaloids, were isolated from the stems and leaves of Daphniphyllum calycinum. The structures of the new compounds 1 and 2 were elucidated on the basis of in-depth spectroscopic-
## Abstract Two new daphniphyllum alkaloids named 2‐hydroxyyunnandaphnine D (**1**) and methyl 7‐hydroxyhomodaphniphyllate (**2**), together with eight known alkaloids, daphnioldhanin D, calyciphylline F, calyciphylline B, deoxycalyciphylline B, daphnicyclidin H, macropodumine C, 9,10‐epoxycalycine
## Abstract Five new polycyclic __Daphniphyllum__ alkaloids, macropodumines F (**1**) and G (**2**), 17‐oxoyuzurimine (**3**), and macropodumines H (**4**) and I (**5**), were isolated from the leaves of __D. macropodum__ Miq., collected in Sichuan Province, China. The structures and relative confi
## Abstract magnified image Four new __Daphniphyllum__ alkaloids, daphlongamines E–H (**1**–**4**, resp.), along with 19 known alkaloids, were isolated from the leaves of __Daphniphyllum longeracemosum.__ Their structures were characterized by spectroscopic methods, especially 2D‐NMR techniques. I