Alkaline Polymerization of Caprolactam. XX. Changes in Catalytic Activity in Activated Alkaline Polymerization of Caprolactam
✍ Scribed by Šebenda, J. ;Masař, B. ;Bukač, Z.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2007
- Weight
- 653 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0449-2994
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In the reaction between the potassium salt of E-caprolactam and N-propionyl-e-caprolactam or N-benzoyl-~-caprolactam in tetrahydrofuran at 25;, the consumption of both reactants and the formation of structures giving ketones by hydrolysis were investigated. Analysis of the data allowed determination
## Abstract Two carbamoyl‐type activators of ε‐caprolactam (CL) anionic polymerization have been used in __quasi__‐adiabatic conditions with sodium caprolactamate as initiator, at different concentrations and relative ratios. The reaction products have been characterized in terms of high‐polymer co