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Anionic polymerization of 6-caprolactam—LVIII. The relative rates of elementary reactions in the activated anionic polymerization of ϵ-caprolactam in tetrahydrofuran

✍ Scribed by J. Stehlíček; T. Šebenda

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
463 KB
Volume
22
Category
Article
ISSN
0014-3057

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✦ Synopsis

In the reaction between the potassium salt of E-caprolactam and N-propionyl-e-caprolactam or N-benzoyl-~-caprolactam in tetrahydrofuran at 25;, the consumption of both reactants and the formation of structures giving ketones by hydrolysis were investigated. Analysis of the data allowed determination of the relative rates of polymerization, of the acylation of amide groups of a linear monomer unit and of the condensation of diacylamino groups.

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