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Alkali Metal Bismuthides ABi and ABi2 — Synthesis, Crystal Structure, Properties.

✍ Scribed by Franziska Emmerling; Nina Laengin; Denis Petri; Martin Kroeker; Caroline Roehr

Publisher
John Wiley and Sons
Year
2004
Weight
56 KB
Volume
35
Category
Article
ISSN
0931-7597

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Synthesis and Crystal Structure of a New
Synthesis and Crystal Structure of a New Alkali Metal Tantalum Sulfide: Na3TaS4
✍ Sabine Herzog; Christian Näther; Peter Dürichen; Wolfgang Bensch 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 93 KB 👁 2 views

Needle-shaped, moisture sensitive, yellow crystals of Na 3 TaS 4 were obtained by the reaction of Na 2 S 3 , Ta, and S at 450 °C. The structure was determined by single crystal X-ray diffraction and refined to R1 and wR2 values of 0.0172 and 0.0381, respectively. Na 3 TaS 4 crystallizes with 32 form