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Alkali earth metal complexes with some macrocyclic “crown” polyethers

✍ Scribed by D.G. Parsons; J.N. Wingfield

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
459 KB
Volume
18
Category
Article
ISSN
0020-1693

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✦ Synopsis

Alkaline earth metal perchlorates and thiocyanates react with cyclic polyethers to yield crystalline solids. The products are found to be influenced by cation radius and charge, and also by the reaction solvent and anion. Competition reactions between potassium and calcium are shown to be solvent dependent.

The perchlorate and thiocyanate anions are shown by infrared spectroscopy to take part in the metal coordination in several complexes.

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