Concise algebraic expressions of the symmetry-adapted functions (SAFs) for both single-valued and double-valued representations are derived for the group chain O ⊃ T ⊃ D 2 ⊃ C 2 and O ⊃ D 4 ⊃ D 2 ⊃ C 2 , which are functions of only the quantum numbers of the respective group chain without involving
Algebraic solutions for the octahedral group: Group chain O⊃C4
✍ Scribed by Peng-Dong Fan; Jin-Quan Chen
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 522 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0020-7608
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✦ Synopsis
Using double-induced representation and eigenfunction method, algebraic expressions are derived for irreducible matrices, projection operators, and symmetry-adapted functions in the group chain O > C for both single-valued and 4 double-valued representations. The simplicity of these expressions lies in the fact that Ž they are functions of the quantum numbers of the corresponding group chain the . analogy of j, m for the group chain SO > SO instead of the irreducible matrix 3 2
elements. The symmetries of the symmetry-adapted functions are disclosed.
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