The relationship between At \* for thermolysis of tertiary alcohols and strain energy change has been extended to compare the strain energy changes associated with the formation of bi-and tricyclic alkyl radicals from the corresponding alkanes.
โฆ LIBER โฆ
Alcohol Thermolysis as a Probe for Comparing Radical Strain Energies
โ Scribed by John S. Lomas; Alain Adenier; Jacques-Emile Dubois
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 57 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0037-9646
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Pyrolysis of dibenzyl ether (I3BE) in tetralin-d, 2 allowed discrimination between possible free radical and concerted reaction mechanisms. Pyrolysis product spectra contained both cr-deuteriotoluene and perprotiotoluene, relative fractions of which were determined, by complementary 'H and '3C n.m.r