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[Al4(OH)2(OCH3)4(H2N-bdc)3]⋅x H2O: A 12-Connected Porous Metal–Organic Framework with an Unprecedented Aluminum-Containing Brick

✍ Scribed by Tim Ahnfeldt; Nathalie Guillou; Daniel Gunzelmann; Irene Margiolaki; Thierry Loiseau; Gérard Férey; Jürgen Senker; Norbert Stock

Book ID: 101570773
Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 418 KB
Volume: 48
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200901409

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Physical stability vs. chemical lability in microporous metal coordination polymers: a comparison of [Cu(OH)(INA)]n and [Cu(INA)2]n: INA = 1,4-(NC5H4CO2)Electronic supplementary information (ESI) available: 1. Structure determination summaries for compounds 1–3. 2. Powder X-ray diffraction patterns: (a) for 1 and (b) for 2 after prolonged heating at different temperatures, establishing framework stabilities and (c) showing transformation of polymer 2 to the molecular compound 3, after 12 h in H2O. Fig. S1: copper coordination environments in compounds 1–3. See http://www.rsc.org/suppdata/cc/b2/b201501n/

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