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[Al4(OH)2(OCH3)4(H2N-bdc)3]⋅x H2O: A 12-Connected Porous Metal–Organic Framework with an Unprecedented Aluminum-Containing Brick

✍ Scribed by Tim Ahnfeldt; Nathalie Guillou; Daniel Gunzelmann; Irene Margiolaki; Thierry Loiseau; Gérard Férey; Jürgen Senker; Norbert Stock

Book ID: 101538289
Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 418 KB
Volume: 121
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200901409

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✦ Synopsis

Abstract

Oktamere Bausteine, die durch organische Liganden zu einem 12er‐Netz verbunden sind, kennzeichnen das vorgestellte stabile Aluminiumaminoterephthalat (siehe Bild). Die Struktur weist eine kubisch‐innenzentrierte Packung auf, in der oktamere Einheiten individuelle Atome ersetzen und dabei verzerrte oktaedrische (rote Kugel) und tetraedrische Käfige (grüne Kugeln) mit effektiven zugänglichen Durchmessern von 1 bzw. 0.45 nm bilden.magnified image

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