Aktivierung von Ti-F-Bindungen in [{C5Me5TiOF}4] und [{C5Me4EtTiOF}4] mit AIMe3
✍ Scribed by Peihua Yu; Prof. Dr. Herbert W. Roesky; Dr. Alojz Demsar; Thomas Albers; Hans-Georg Schmidt; Dr. Mathias Noltemeyer
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 239 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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Synthesis and Structure of CpAIClz Compounds with Sterically Demanding Substituents (Cp = Me&, EtMe,C,)['' The compounds Cp\*AICl2 (3) (Cp\* = Me5C5) and Cp'A1CI2 (4) (Cp' = EtMe,C,) have been prepared by the reaction of Cp\*SiMe3 (1) and Cp'SiMe3 (2) with AIC13. The single-crystal X-ray structures
Inhaltsu È bersicht. t-Bu 4 Sb 4 reagiert mit Fe 2 (CO) 9 zu [(t-Bu 4 Sb 4 )Fe(CO) 4 ] (1). [(t-Bu 4 Sb 4 )Mo(CO) 5 ] (2) wird aus (thf)Mo(CO) 5 und t-Bu 4 Sb 4 gebildet. [(t-Bu 3 Sb 4 )Mo(g 5 -C 5 Me 5 )(CO) 3 ] (3) ist ein Produkt der Reaktion von t-Bu 4 Sb 4 und [(g 5 -C 5 Me 5 )Mo(CO) 3 ] 2 . Ûb