Synthesen und Kristallstrukturen von [(t-Bu4Sb4)Fe(CO)4], [(t-Bu4Sb4)Mo(CO)5] und [(t-Bu3Sb4)Mo(η5-C5Me5)(CO)3]

✍ Scribed by H. J. Breunig; R. Rösler; E. Lork

• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: German
• Weight: 114 KB
• Volume: 625
• Category: Article
• ISSN: 0372-7874
• DOI: 10.1002/(sici)1521-3749(199910)625:10<1619::aid-zaac1619>3.0.co;2-t

✦ Synopsis

Inhaltsu È bersicht. t-Bu 4 Sb 4 reagiert mit Fe 2 (CO) 9 zu [(t-Bu 4 Sb 4 )Fe(CO) 4 ] (1). [(t-Bu 4 Sb 4 )Mo(CO) 5 ] (2) wird aus (thf)Mo(CO) 5 und t-Bu 4 Sb 4 gebildet. [(t-Bu 3 Sb 4 )Mo(g 5 -C 5 Me 5 )(CO) 3 ] (3) ist ein Produkt der Reaktion von t-Bu 4 Sb 4 und [(g 5 -C 5 Me 5 )Mo(CO) 3 ] 2 . Ûber die Kristallstrukturen von 1±3 wird berichtet. Syntheses and Crystal Structures of [(t-Bu 4 Sb 4 )Fe(CO) 4 ], [(t-Bu 4 Sb 4 )Mo(CO) 5 ], and [(t-Bu 3 Sb 4 )Mo(g 5 -C 5 Me 5 )(CO) 3 ] Abstract. t-Bu 4 Sb 4 reacts with Fe 2 (CO) 9 to form [(t-Bu 4 Sb 4 )Fe(CO) 4 ] (1). [(t-Bu 4 Sb 4 )Mo(CO) 5 ] (2) is formed from (thf)Mo(CO) 5 and t-Bu 4 Sb 4 . [(t-Bu 3 Sb 4 )Mo(g 5 -C 5 Me 5 )(CO) 3 ] (3) is a product of the reaction of t-Bu 4 Sb 4 with [(g 5 -C 5 Me 5 )Mo(CO) 3 ] 2 . The crystal structures of 1±3 are reported.