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Air-Stable, Storable, and Highly Selective Chiral Lewis Acid Catalyst.

✍ Scribed by Masaharu Ueno; Haruro Ishitani; Shu Kobayashi

Publisher
John Wiley and Sons
Year
2003
Weight
199 KB
Volume
34
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis and Appli
ChemInform Abstract: Synthesis and Application of the First Chiral and Highly Lewis Acidic Silyl Cationic Catalyst.
✍ M. JOHANNSEN; K. A. JOERGENSEN; G. HELMCHEN πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 1 views

Synthesis and Application of the First Chiral and Highly Lewis Acidic Silyl Cationic Catalyst. -Cationic silyl compounds containing a chiral dimethylbinaphthyl backbone are synthesized and used as highly active Lewis acid catalysts for (hetero) Diels-Alder reactions with modest enantioselectivity.