AIBN-Catalyzed Oxidative Cleavage of gem -Disubstituted Alkenes with O 2 as an Oxidant
โ Scribed by Wang, Guang-Zu; Li, Xing-Long; Dai, Jian-Jun; Xu, Hua-Jian
- Book ID
- 127390089
- Publisher
- American Chemical Society
- Year
- 2014
- Tongue
- English
- Weight
- 909 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract A new, general method for the synthesis of phenanthridines has been developed by palladiumโcatalyzed oxidative remote C๏ฃฟH olefinationโcarboaminationโC๏ฃฟC bond cleavage tandem reaction. It is noteworthy that alkenes are used as the oneโcarbon resources for this tandem reaction.
tic-Diols were oxidized with aqueous hydrogen peroxide in the presence of heteropolyacids to yield carboxylic acids as main products in good yields. Although the oxidation proceeded via cw-ketol or cu-diketone intermediates, another oxidation path such as direct C-C bond cleavage is suggested in the