Palladium-Catalyzed Oxidative CC Bond Cleavage Cyclization of Biaryl-2-amines with Alkenes Involving CH Olefination and Carboamination

✍ Scribed by Yan-Yun Liu; Ren-Jie Song; Cui-Yan Wu; Lu-Bin Gong; Ming Hu; Zhi-Qiang Wang; Ye-Xiang Xie; Jin-Heng Li

• Book ID: 101425582
• Publisher: John Wiley and Sons
• Year: 2012
• Tongue: English
• Weight: 345 KB
• Volume: 354
• Category: Article
• ISSN: 1615-4150
• DOI: 10.1002/adsc.201100651

✦ Synopsis

Abstract

A new, general method for the synthesis of phenanthridines has been developed by palladium‐catalyzed oxidative remote CH olefination–carboamination–CC bond cleavage tandem reaction. It is noteworthy that alkenes are used as the one‐carbon resources for this tandem reaction.