✦ LIBER ✦

Aggregation of carbamato ligands around the [Co4O]6+ core. Synthesis and structure of the cluster [Co4O(O2CNC9H18)6] prepared by a novel oxo-transfer reaction of the nitroxyl free radical 2,2,6,6-tetramethylpiperidin-1-oxyl with [Co2(CO)8]

✍ Scribed by Jaitner, Peter; Rieker, Christopher; Wurst, Klaus

Book ID: 126241383
Publisher: Royal Society of Chemistry
Year: 1997
Tongue: English
Weight: 84 KB
Volume: 13
Category: Article
ISSN: 1359-7345
DOI: 10.1039/A701238A

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Lewis basicity of the [Co4O4]4+ cubane c

Lewis basicity of the [Co4O4]4+ cubane core. Preparation of a mixed-valence (4Co II , 4Co III ) cluster with an unusual [Co8(�4-O)4]2+ core, and new [Co4O3(OH)]5+ and [Co4O2(OH)2]6+ cubane complexes

✍ Dimitrou, Katerina; Folting, Kirsten; Streib, William E.; Christou, George 📂 Article 📅 1994 🏛 The Royal Society of Chemistry 🌐 English ⚖ 330 KB

Chains and Nanochannels Self-Assembled f

Chains and Nanochannels Self-Assembled from Carbido Clusters, Silver Ions and Heterocyclic Ligands – Crystal Structures of the 1D Coordination Polymers [{AgOC4H8{Rh6C(CO)15}AgOC4H8}pyz]∞ and [bipy{Ag2Ru6C(CO)16}(bipy)2{Ag2Ru6C(CO)16}·2C4H8O]∞

✍ Roberto Della Pergola; Annalisa Sironi; Carlo Manassero; Mario Manassero 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 459 KB 👁 1 views

## Abstract Two prototypical carbido anionic clusters, the prismatic [Rh~6~C(CO)~15~]^2–^ and the octahedral [Ru~6~C(CO)~16~]^2–^, can add two electrophilic Ag–NCMe^+^ fragments, which were exploited to condense the clusters with bifunctional heterocyclic ligands, such as pyrazine (pyz) or 4,4′‐bip

The chemistry of cobalt acetate. X. The

The chemistry of cobalt acetate. X. The preparations of the mixed ligand cobalt oligomers, [Co3O(C6H5N2O)3(CH3CO2)3][PF6].CH3CN (I), [Co4(μ2-OH)2(η1:η1:μ2-CH3COO)2(CH3CO2)2 (η1:η1:μ2-C11H8NO)2(η1:η1:η1:η1:μ2-C11H8N3O)2][PF6]2.CH3OH.3H2O (II) and [Co3O(CH3CO2)5(C7H6NO2)(py)3][PF6] (III) and the crystal structures of (I) and (II). Comparisons with homoleptic cobalt acetate dimers and trimers

✍ Kaza, Arati; Jensen, Paul; Clegg, Jack; Masters, Anthony F.; Maschmeyer, Thomas; 📂 Article 📅 2013 🏛 Elsevier Science 🌐 English ⚖ 406 KB

Cation-Directed Synthesis of Tungstosili

Cation-Directed Synthesis of Tungstosilicates. 1. Syntheses and Structures of K 10 A-α-[SiW 9 O 34 ]·24H 2 O, of the Sandwich-Type Complex K 10.75 [Co(H 2 O) 6 ] 0.5 [Co(H 2 O) 4 Cl] 0.25 A-α-[K 2 {Co(H 2 O) 2 } 3 (SiW 9 O 34 ) 2 ]·32H 2 O and of Cs 15 [K(SiW 11 O 39 ) 2 ]·39H 2 O

✍ Laronze, Nathalie; Marrot, Jérôme; Hervé, Gilbert 📂 Article 📅 2003 🏛 American Chemical Society 🌐 English ⚖ 144 KB

Phosphine Ligand Attack at Both the Meth

Phosphine Ligand Attack at Both the Methylidyne Cap and the CpNi Center in HCCo 2 NiCp(CO) 6 by 2,3-Bis(diphenylphosphino)maleic Anhydride (bma): P−C Bond Cleavage Reactivity, Kinetics, and X-ray Structures of the Zwitterionic Clusters Co 2 NiCp(CO) 4 (μ-CO)[μ 2 ,η 2 ,η 1 -C(H)PPh 2 CC(PPh 2 )C(O)OC(O)] and Co 2 NiCp(CO) 4 [μ 2 ,η 2 ,σ-C(H)PPh 2 CCC(O)OC(O)](μ 2 -PPh 2 )

✍ Bott, Simon G.; Yang, Kaiyuan; Talafuse, Kathleen A.; Richmond, Michael G. 📂 Article 📅 2003 🏛 American Chemical Society 🌐 English ⚖ 148 KB

Cation-Directed Synthesis of Tungstosili

Cation-Directed Synthesis of Tungstosilicates. Part 1. Syntheses and Structures of K10A-α- [SiW9O34]×24H2O, of the Sandwich-Type Complex K10.75[Co(H2O)6]0.5 [Co(H2O)4Cl]0.25A-α- [K2{Co(H2O)2}3 (SiW9O34)2]×32H2O and of Cs15 [K(SiW11O39)2]×39H2O.

✍ Nathalie Laronze; Jerome Marrot; Gilbert Herve 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 103 KB 👁 1 views