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Aggregation and Polymerization of Amphiphilic Macromonomers with a Double Bond at the Hydrophilic Terminal

✍ Scribed by S. Maiti; P.R. Chatterji

Book ID: 102585684
Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 102 KB
Volume: 232
Category: Article
ISSN: 0021-9797
DOI: 10.1006/jcis.2000.7209

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✦ Synopsis

Macromonomers with general formula C n [EO]

m -CO-CH= =CH 2 were synthesized by endcapping corresponding Brij compounds with acryloyl chloride. Their aggregation behavior evaluated against the parent Brij compounds, the saturated and triblock analogs advocate that the terminal double bond is protected by the partially looped PEG chain. The homo-and copolymerization behavior in aqueous media is consistent with this possibility.

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