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Ageing of EPDM—2. Role of hydroperoxides in photo- and thermo-oxidation

✍ Scribed by F. Delor; G. Teissedre; M. Baba; J. Lacoste


Book ID
108400358
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
852 KB
Volume
60
Category
Article
ISSN
0141-3910

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The role of hydroperoxides in photo-oxid
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Hydroperoxides undergo various types of homolytic reactions on exposure to u.v. radiation. Free radicals formed from the photodecomposition of the hydroperoxide group (OOH) are oxy (HO.) and peroxy (HOO.) radicals which participate in further reactions. In cis-l,4-polybutadiene, they may initiate fr