Aerobic Oxidations Catalyzed by Polyoxometalates
β Scribed by A. M. Khenkin; R. Ben-Daniel; A. Rosenberger; I. Vigdergauz; R. Neumann
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 4 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
An Anderson-type polyoxometalate, [I VII Mo 6 O 24 ] 5Β± , has been used as a catalyst for the aerobic oxidation at 80 8C of vicinal diols (glycols). This is the first report on the use of such a polyoxometalate as an oxidation catalyst. Reactivity and selectivity were dependent on the substrate. Thu
## Abstract Cyclometallated palladium compounds with pyridine were shown to serve as more efficient catalysts for the aerobic oxidation of 1βphenylethanol than a previously investigated analogue with an oxazoline ring. Substituents with different electronic properties in the phenyl ring were shown