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Aerobic Oxidation of Benzyl Alcohols Catalyzed by Aryl Substituted N-Hydroxyphthalimides. Possible Involvement of a Charge-Transfer Complex

โœ Scribed by Annunziatini, Claudia; Gerini, Maria Francesca; Lanzalunga, Osvaldo; Lucarini, Marco


Book ID
111943139
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
160 KB
Volume
69
Category
Article
ISSN
0022-3263

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The catalync p-benzoqumone or au oxldaaon of benzoin to bennl was camed out m the presence of Pen&-o-xyl)#-(o-xyl = o-xylene-a. a'-&thlolate) or [Fen(S+Bu)&-m a ratlo [benzomlficatalyst] = 20/l m DMF at 25 'C Under such mild reacnon condmons, the Fe(II) thiolate complex exhibited high catalync activ