✦ LIBER ✦

A new, highly selective synthesis of aromatic aldehydes by aerobic free-radical oxidation of benzylic alcohols, catalysed by n-hydroxyphthalimide under mild conditions. Polar and enthalpic effects

✍ Scribed by Minisci, Francesco; Punta, Carlo; Recupero, Francesco; Fontana, Francesca; Pedulli, Gian Franco

Book ID: 111676443
Publisher: Royal Society of Chemistry
Year: 2002
Tongue: English
Weight: 123 KB
Volume: 7
Category: Article
ISSN: 1359-7345
DOI: 10.1039/b110451a

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: A New, Highly Selec

ChemInform Abstract: A New, Highly Selective Synthesis of Aromatic Aldehydes by Aerobic Free-Radical Oxidation of Benzylic Alcohols, Catalyzed by N-Hydroxyphthalimide under Mild Conditions. Polar and Enthalpic Effects.

✍ Francesco Minisci; Carlo Punta; Francesco Recupero; Francesca Fontana; Gian Fran 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

A new selective free radical synthesis o

A new selective free radical synthesis of aromatic aldehydes by aerobic oxidation of tertiary benzylamines catalysed by N-hydroxyimides and Co(II) under mild conditions. Polar and enthalpic effects

✍ Andrea Cecchetto; Francesco Minisci; Francesco Recupero; Francesca Fontana; Gian 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 107 KB

Tertiary benzylamides are easily and selectively converted into aldehydes by molecular oxygen; the reaction is catalysed by N-hydroxyamides and Co(II).

A New, Highly Selective, Free-Radical Ae

A New, Highly Selective, Free-Radical Aerobic Oxidation of Silanes to Silanols Catalyzed by N-Hydroxyphthalimide under Mild Conditions.

✍ Francesco Minisci; Francesco Recupero; Carlo Punta; Chiara Guidarini; Francesca 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

Polar effects in free-radical reactions.

Polar effects in free-radical reactions. A novel homolytic acylation of heteroaromatic bases by aerobic oxidation of aldehydes, catalysed by N-hydroxyphthalimide and Co salts

✍ Francesco Minisci; Francesco Recupero; Andrea Cecchetto; Carlo Punta; Cristian G 📂 Article 📅 2003 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 41 KB

## Abstract A new process for the homolytic acylation of protonated heteroaromatic bases is described; an N‐oxyl radical (PINO) generated from __N__‐hydroxyphthalimide by air oxygen and Co(II) abstracts a hydrogen atom from an aldehyde. The resulting nucleophilic acyl radical adds to a heteroaromat

Mechanisms of the Aerobic Oxidation of A

Mechanisms of the Aerobic Oxidation of Alcohols to Aldehydes and Ketones, Catalysed under Mild Conditions by Persistent and Non-Persistent Nitroxyl Radicals and Transition Metal Salts − Polar, Enthalpic, and Captodative Effects

✍ Francesco Minisci; Francesco Recupero; Andrea Cecchetto; Cristian Gambarotti; Ca 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 189 KB

## Abstract The oxidation of alcohols to aldehydes and ketones by air or oxygen under mild conditions (room temperature and atmospheric pressure), catalysed by persistent and non‐persistent nitroxyl radicals in combination with transition metal salts, appears to be the most convenient of the numero

Solvent and Temperature Effects in the F

Solvent and Temperature Effects in the Free Radical Aerobic Oxidation of Alkyl and Acyl Aromatics Catalysed by Transition Metal Salts and N-Hydroxyphthalimide: New Processes for the Synthesis of p-Hydroxybenzoic Acid, Diphenols, and Dienes for Liquid Crystals and Cross-Linked Polymers

✍ Minisci, Francesco; Recupero, Francesco; Cecchetto, Andrea; Gambarotti, Cristian 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 98 KB