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Advances in the Synthesis of Aryltetralin Lignan Lactones

✍ Scribed by Jonathan D. Sellars; Patrick G. Steel

Publisher: John Wiley and Sons
Year: 2007
Weight: 11 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200744227

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Advances in the Synthesis of Aryltetrali

Advances in the Synthesis of Aryltetralin Lignan Lactones

✍ Jonathan D. Sellars; Patrick G. Steel 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 313 KB 👁 1 views

## Abstract Etoposide and tenoposide, derivatives of the aryltetralin lignan lactone podophyllotoxin (**5**), are clinically important anticancer agents. The structure of podophyllotoxin includes four contiguous chiral centres contained within a stereochemically unstable __trans__‐fused tetrahydron

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Asymmetric Synthesis of a Lignan Lactone from a meso Anhydride. -A hitherto unknown method for the asymmetric synthesis of cis-lactones like (X) via the meso-anhydride (VI) is described. -(WARD, R.