Advanced Two-Dimensional Material-Based Heterostructures in Sustainable Energy Storage Devices

✍ Scribed by Ponnada S., Naskar S. (ed.)

• Publisher: CRC Press
• Year: 2025
• Tongue: English
• Leaves: 220
• Category: Library

✦ Synopsis

Advanced Two-Dimensional Material-Based Heterostructures in Sustainable Energy Storage Devices provides a detailed overview of advances and challenges in the development of 2D materials for use in energy storage devices. It offers deep insight into the synthesis, characterization, and application of different 2D materials and their heterostructures in a variety of energy storage devices, focusing on new phenomena and enhanced electrochemistry.
This book:
Introduces 2D materials, synthesis methods, and characterization techniques.
Discusses application in a wide range of batteries and supercapacitors.
Offers perspectives on future investigations necessary to overcome existing challenges.
This comprehensive reference is written to guide researchers and engineers working to advance the technology of energy-efficient energy storage devices.

✦ Table of Contents

Cover
Half Title
Advanced Two-Dimensional Material-Based Heterostructures in Sustainable Energy Storage Devices
Copyright
Contents
Preface
About the Editors
Contributors
1. Introduction and Characterization of Two-Dimensional Materials
1.1 Introduction
1.2 Types of 2D Nanomaterials and Typical Characterization Techniques
1.2.1 Metal-Free 2D Nanomaterials
1.2.1.1 Graphene and Related C-Based Materials
1.2.1.2 Boron-Based Materials
1.2.1.3 Phosphorous-Based Materials
1.2.2 2D Metallic Nanomaterials
1.2.2.1 2D Metals and Alloys
1.2.2.2 2D Metal Oxides
1.2.2.3 2D Metal Carbide/Nitride and MXenes
1.2.2.4 Transition Metal Dichalcogenides
1.2.2.5 2D Metal-Organic Framework
1.3 Conclusion
Acknowledgements
Conflicts of Interest
References
2. Introduction to Batteries and Supercapacitors
2.1 Introduction to Batteries
2.1.1 History of Batteries
2.1.2 Basic Principles of Batteries
2.1.3 Types of Batteries
2.1.3.1 Primary Batteries
2.1.3.2 Secondary Batteries
2.1.3.2.1 Lead-Acid Batteries
2.1.3.2.2 Nickel-Cadmium Batteries
2.1.3.2.3 Silver Zinc Energy Storage Device
2.1.3.2.4 Lithium-Ion Batteries
2.1.3.2.5 Alkaline Batteries
2.1.3.2.6 Flow Batteries
2.1.3.2.7 Solid-State Batteries
2.1.4 Conclusion
2.1.5 Future Developments
2.1.6 Environmental Considerations
2.1.7 Applications of Batteries
2.1.7.1 Portable Electronics
2.1.7.2 Electric Vehicles
2.1.7.3 Renewable Energy Systems
2.1.7.4 Medical Devices
2.1.7.5 Military and Aerospace
2.2 Introduction to Capacitors
2.2.1 Classification and Working Principle
2.2.1.1 Capacitors
2.2.1.2 Ceramic Capacitors
2.2.1.3 Polymer Capacitors
2.2.1.4 Electrolytic Capacitors
2.2.2 Energy Storage Mechanism in Capacitors
2.2.2.1 Double-Layer Capacitors
2.2.2.2 Charge Storage as Pseudo-Capacitance
2.2.2.3 Hybrid Capacitors
2.2.3 Electrode Materials: Capacitors
2.2.3.1 Activated Carbon
2.2.3.2 Metal Oxides
2.2.4 Materials for Current Collector
2.2.5 Electrolytes
2.2.6 Idea and Introduction of Supercapacitors
2.2.6.1 Redox Electrochemical Capacitors
2.2.7 Characteristics and Features of Supercapacitors
2.2.7.1 Power Density
2.2.7.2 Energy Density
2.2.7.3 Analysis by Equivalent Circuit Analysis
2.2.7.4 Efficiency
2.2.8 Materials for Supercapacitor Development
2.2.8.1 Positive Electrode
2.2.8.2 Negative Electrode
2.2.9 Economic Scale of Supercapacitors
2.2.10 Conclusion
Acknowledgement
Conflicts of Interest
References
3. Two-Dimensional Materials in Lithium-Ion Batteries
3.1 Introduction
3.2 Role of 2D Materials in LIBs
3.2.1 Graphene
3.2.2 TMOs
3.2.3 TMDs
3.2.4 MXenes
3.2.5 Xenes
3.3 Conclusion and Future Aspects
Acknowledgments
Declaration of Competing Interest
References
4. Two-Dimensional Materials in Lithium-Sulfur Batteries
4.1 Introduction
4.2 The Significance of Sulfur in Li-S Batteries and Their Limitations
4.3 2D Materials to Suppress the Shuttling of Polysulfides
4.3.1 Graphene
4.3.2 Graphitic Carbon Nitride and Boron Nitride
4.3.3 Phosphorene
4.3.4 Transition Metal Dichalcogenides
4.3.5 MXene
4.3.6 Biphenylene
4.4 Conclusion
Acknowledgments
Conflicts of Interest
References
5. Two-Dimensional Materials in Lead-Tin Alloys in Li Batteries
5.1 Introduction
5.2 General Characteristics (Properties) of Tin and Lead as Anode Materials
5.3 Progress of 2D Anode Materials Pb and Sn Alloys for Li-Ion
5.3.1 Pb-Based 2D Anode Materials
5.3.2 Sn-Based 2D Anode Materials
5.3.3 Pb-Sn-Based 2D Anode Materials
5.4 Synthesis of Pb-Sn-Based Two-Dimensional Anode Materials
5.4.1 Mechanical Exfoliation
5.4.2 Liquid-Phase Exfoliation (LPE)
5.4.3 Solution-Phase Growth
5.4.4 Chemical Vapor Deposition
5.5 Conclusion
Acknowledgements
Conflicts of Interest
References
6. Two-Dimensional Materials in Metal-Air Batteries
6.1 Introduction
6.1.1 Metal-Air Batteries
6.1.2 Challenges of Metal-Air Batteries
6.1.3 Mechanism of ORR/OER
6.1.4 Requirements for ORR/OER Electrocatalyst in Metal-Air Batteries
6.1.5 Classification of Electrocatalysts for ORR/OER
6.2 2D Materials as Electrocatalysts for Metal-Air Batteries
6.3 Experimental and Case Studies of 2D Materials for Metal-Air Batteries
6.3.1 Preparation Methods of 2D Materials
6.3.1.1 Exfoliation-Related Methods
6.3.1.2 Chemical Vapor Deposition (CVD) Methods
6.3.1.3 Epitaxial Growth Methods
6.3.2 Performance Evaluation of 2D Material-Based Metal-Air Batteries
6.3.2.1 Graphene-Based Materials
6.3.2.2 Transition Metal Chalcogenides
6.3.2.3 Transition Metal Carbides, Nitrides, and Carbon Nitirdes (Mxenes)
6.4 Outlook on Future Research Directions
Acknowldgements
Conflicts of Interest
References
7. Two-Dimensional Materials in Na-Ion Batteries
7.1 Background and Recent Progresses in Sodium-Ion Batteries
7.2 Sodium-Ion Batteries - Working Principle, Advantages, and Disadvantages
7.3 Two-Dimensional (2D) Nanomaterials Used in Sodium-Ion Batteries
7.4 Application of 2D Materials in Various Components of Sodium-Ion Batteries
7.4.1 Anode Materials
7.4.1.1 Graphene
7.4.1.2 MXenes (Metal Carbide and Nitride)
7.4.1.3 Transition Metal Dichalcogenides (TMDs)
7.4.2 Cathode Materials
7.4.2.1 Layered Transition Metal Oxides (TMO)
7.4.2.2 Metal Phosphates
7.4.3 Solid Electrolytes
7.5 Conclusion
Conflicts of Interest
References
8. Two-Dimensional Materials for Flexible Batteries
8.1 Introduction
8.2 Basics of Batteries: Components and Working Principle
8.3 Common Challenges with LIBs
8.4 Why 2D Materials? Advantages over Current Materials
8.5 2D Materials: Synthesis of Graphene/TMDs Materials and Their Heterostructures
8.6 Recent Developments in Graphene/TMDs Composites: Applications in Batteries as Anode/Cathode Examples
8.7 Limitations and Future Perspectives
Acknowledgments
Declaration of Competing Interest
References
9. Two-Dimensional Materials for Supercapacitor Applications
9.1 Introduction
9.1.1 Nanostructured Carbon-Based Materials
9.1.2 MXene-Based Materials
9.1.3 Transition Metal Dichalcogenide-Based Materials
9.1.4 Black Phosphorus
9.1.5 Hexagonal Boron Nitride
9.1.6 Carbon Nitride
9.1.7 Metal Oxides/Hydroxides
9.2 Challenges
9.3 Conclusion
Acknowledgments
Conflicts of Interest
References
Index