Adsorption of proline on a mercury electrode in neutral solution
✍ Scribed by M.M. Gómez; R. Motilla; E. Díez
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 768 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
✦ Synopsis
Ah&set-The adsorption of proline on mercury in aqueous solutions of KtZlO, lo-' M has been studied by means of double layer capacity, potential of zero charge and surface tensions at pzc measurements. The compound shows the typical characteristic features of an organic adsorbate and obeys a Frumkin isotherm with the interaction parameter depending on the eteetric field. The maximum adsorption ocxmrs at u"= -7 eC cm-z and the value of the standard free energy at this charge is -14.4 kJ mol-'.
📜 SIMILAR VOLUMES
The specific adsorption of penicillin G (salt K) on the mercury in aqueous solution has been determined from electrocapillary and capacity measurements. The adsorption of penicillinium anions can be fitted by a Frumkin isotherm with a value of -3.5 for the interaction parameter. The standard Gibbs e
It is shown that if the shape of the adsorption isotherm does not depend on the electrode potential q and the double layer capacitance C decreases to a certain limiting value with increasing concentration of the organic substance, the energy of adsorption is a quadratic function of p. In this case,