𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Adsorption of chloride ion at the mercury/ solution interface in LiCl—methanol and HCl—ethanol systems—III

✍ Scribed by J. Jastrzebska

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
534 KB
Volume
18
Category
Article
ISSN
0013-4686

No coin nor oath required. For personal study only.

✦ Synopsis

The distance ratio of the inner and outer Helmholtz planes, estimated previously from the capacitance ratio method, has been additionally determined as h-values,* from the reduced isotherm (virial and Langmuir types) with the Frumkin-isotherm results of individual q,$and q&data. Similarly, the so-called chemical term of adsorption energy (Stern's adsorption potential) was evaluated in the investigated systems, using the isotherm parameters.

📜 SIMILAR VOLUMES

Adsorption of chloride ion at the mercur
Adsorption of chloride ion at the mercury/solution interface in LiCl-methanol and HCl-ethanol systems—II
✍ J. Jastrzȩbska 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 739 KB

In order to describe the adsorption of the Cl-ion at a mercury electrode in methanol and in ethanol more accurately, some additional properties of the inner layer were determined using Parsons' a-function data (collected in part I), the c&. values, and the thickness ratio parameters. The solvent eff

On the kinetics of adsorption and desorp
On the kinetics of adsorption and desorption of perchlorate ions in the presence of 3-methyl-isoquinoline at the mercury—aqueous solution interface
✍ J. Lipkowski; G. Quarin; Cl. Buess-Herman 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 611 KB

Ahtract-Coadsorption of perchlorate ions and 3-methyl-isoquinoline molecules at the mercury-aqueous solution interface results in the formation of a condensed film. The process of ClO; incorporation (or removal) is very slow. Characteristic relaxation times (about 10-l s) are several orders of magni