Adsorption-desorption studies using ESD of CCl2F2, C2H2F2 and C2F6 on tungsten
โ Scribed by Mario A.B. De Moraes; David Lichtman
- Publisher
- Elsevier Science
- Year
- 1985
- Weight
- 57 KB
- Volume
- 160
- Category
- Article
- ISSN
- 0167-2584
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๐ SIMILAR VOLUMES
Rate constants for the reactions of atomic oxygen ( 0 3 P ) with C&3F, C&IaCl,C@3Br, 1, l-CzHzFz, and I ,2-C&IzFz have been measured at 307' K using a discharge-flow system coupled to a mass spectrometer. The rate constants for these reactions are (in units of 1011cm3mole-1s-1)2.63 &0.38,5.22 =tO0.2
Ab initio MO calculations have been performed for neutral and cationic CzHzFz structures. Olefinic and carbene structures are investigated for the neutral isomers, while olefinic, carbene, and fluoronium-type cations are found. Stability orders and rotational barriers are discussed in terms of orbit