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Additions and Corrections - The Juvenile Hormone. V. Synthesis of the Racemic Juvenile Hormone.

✍ Scribed by Dahm, Karl Heinz.; Trost, Barry M.; Röller, Herbert.


Book ID
127386920
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
145 KB
Volume
89
Category
Article
ISSN
0002-7863

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Synthesis of racemic [2-14C] insect juve
✍ Paul H. Adams 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 French ⚖ 287 KB

Both racemic [2-14C] juvenile hormone 111 (JH 111; methyl-l0,11-epoxy-3,7,11t rimethyl-2(E) , 6 ( E ) [2-14C]dodecadienoate) and its 2-(2) isomer were synthesised on a 1 millimolar scale by forming the 9,lO epoxide of geranyl acetone and reacting this with the anion of trimethylphosphon0-[2-~~C]acet