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Additions and Corrections - Degenerate Thermal Rearrangement of Bicyclo[5.3.0 4,8 ]-deca-2,5,9-triene (Lumibullvalene)

✍ Scribed by Paquette, Leo A.; Kukla, Michael J.

Book ID
125941348
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
247 KB
Volume
95
Category
Article
ISSN
0002-7863

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✍ Hendrik Disteldorf; Jens Renner; Heinrich Heydt; Paul Binger; Manfred Regitz 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB

## Abstract 1,5,8‐Triphosphaisolumibullvalenes (1,5,8‐triphosphatetracyclo[4.4.0.0^2,8^.0^5,7^]deca‐3,9‐dienes) **3**, when suitably substituted, undergo thermal rearrangement to afford the 1,1b,2a‐triphosphahomoquadricyclanes (tetrahydro‐1__H__‐1,1b,2a‐triphosphadicyclopropa[__cd__,__gh__]‐pentale