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Additions and Corrections: 2,3,5-Tri-O-benzyl-D-ribosyl and -L-arabinosyl Bromides

✍ Scribed by Barker, Robert; Fletcher, Jr., Hewitt


Book ID
127060053
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
125 KB
Volume
27
Category
Article
ISSN
0022-3263

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Stereoselective synthesis of 4-C-methyl-
✍ Serge H Boyer; Bheemarao G Ugarkar; Mark D Erion πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 231 KB

Sugar intermediates 4-C-methyl-2,3,5-tri-O-benzyl-D-ribofuranose (8b) and 4-C-methyl-2,3,5-tri-O-benzyl-L-lyxofuranose (8a) were synthesized by addition of alkylithium reagents to pentanones 3a,b. The nucleophilic additions proceeded with good stereoselectivity and good yields to give the titled com