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2,3,5-Tri-O-benzyl-D-ribosyl and -L-arabinosyl Bromides

✍ Scribed by BARKER, ROBERT; FLETCHER, HEWITT G.


Book ID
126310155
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
668 KB
Volume
26
Category
Article
ISSN
0022-3263

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Sugar intermediates 4-C-methyl-2,3,5-tri-O-benzyl-D-ribofuranose (8b) and 4-C-methyl-2,3,5-tri-O-benzyl-L-lyxofuranose (8a) were synthesized by addition of alkylithium reagents to pentanones 3a,b. The nucleophilic additions proceeded with good stereoselectivity and good yields to give the titled com