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Addition of trimethylsilyl enol ethers to isoquinolinium salts: a facile synthesis of 1-(2-oxoalkyl)-2-(ethoxycarbonyl)(or acetyl)-1,2-dihydroisoquinolines and their cyclization for the synthesis of isoquinoline alkaloid skeleton

โœ Scribed by Akiba, Kinya; Nakatani, Masayuki; Wada, Makoto; Yamamoto, Yohsuke


Book ID
121876408
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
875 KB
Volume
50
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


Addition of boron enolates to isoquinoli
โœ Kin-ya Akiba; Kei-ichi Araki; Masayuki Nakatani; Makoto Wada ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 259 KB

An efficient method to synthesize 1-P-keto substituted 2-ethoxycarbonyl ( or 2-acetyl )-1, 2-dihydroisoquinolines (A) is described, utilizing boron enolates and isoquinolinium salts. The products were treated with sodium ethoxide to afford