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Addition of oxygen- and sulfur-centered radicals to [1.1.1]propellane

✍ Scribed by McGarry, P. F.; Johnston, L. J.; Scaiano, J. C.

Book ID
125996819
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
400 KB
Volume
54
Category
Article
ISSN
0022-3263

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## Abstract Phosphorus‐ or sulfur‐centered radicals generated from the reaction of manganese(III) acetate with dialkyl phosphonates or arylthiols undergo selective additions to conjugated alkynes followed by cyclization and rearomatization to afford 2‐phosphonyl‐ or 2‐thioaryl‐substituted indenones