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Addition of organotin hydrides across the nitrogen-nitrogen double bond; Hydrogenolysis of the tin-nitrogen bond by organotin hydrides

✍ Scribed by J. G. Noltes


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
313 KB
Volume
83
Category
Article
ISSN
0165-0513

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Investigations on organo-tin compounds.
✍ van der Kerk, G. J. M. ;Noltes, J. G. ;Luijten, J. G. A. πŸ“‚ Article πŸ“… 2007 πŸ› Wiley (John Wiley & Sons) βš– 853 KB

## Abstract A new method for the synthesis of tin‐carbon bonds is described. The synthesis involves the non‐catalysed addition of organo‐tin hydrides to olefinic double bonds at moderate temperatures (60–100Β°). This method allows the preparation of a variety of hitherto unknown types of functionall

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There are two possible limiting mechanisms by which compounds containing the carbonnitrogen double bond can thermally isomerize. One of these, proposed for the isomerization of imines2, involves a lateral in-plane shift of the group bonded to the imino nitrogen. The transition state for this proces