Addition of organotin hydrides across the nitrogen-nitrogen double bond; Hydrogenolysis of the tin-nitrogen bond by organotin hydrides
β Scribed by J. G. Noltes
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 313 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0165-0513
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## Abstract A new method for the synthesis of tinβcarbon bonds is described. The synthesis involves the nonβcatalysed addition of organoβtin hydrides to olefinic double bonds at moderate temperatures (60β100Β°). This method allows the preparation of a variety of hitherto unknown types of functionall
There are two possible limiting mechanisms by which compounds containing the carbonnitrogen double bond can thermally isomerize. One of these, proposed for the isomerization of imines2, involves a lateral in-plane shift of the group bonded to the imino nitrogen. The transition state for this proces