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Addition of organosilicon halides, pseudohalides and amides to acetonitrile oxide

✍ Scribed by Robert F. Cunico; Louis Bedell


Book ID
103222867
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
399 KB
Volume
281
Category
Article
ISSN
0022-328X

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Oxidative addition of trifluoromethyl ha
✍ A.J. Blake; E.A.V. Ebsworth; J.H. Holloway; M.J. Rieland πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 29 KB

IK(I)-and Rh(I)-complexes react with CF3-halides to give oxidative addition products. In the reaction of IrX(CO)(PEt3)2 with CF31, X = Cl, Br, I, and with CF3Br, X = Cl, Br, only the tram addition products are formed.