Oxidative addition of trifluoromethyl ha
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A.J. Blake; E.A.V. Ebsworth; J.H. Holloway; M.J. Rieland
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Article
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1989
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Elsevier Science
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English
β 29 KB
IK(I)-and Rh(I)-complexes react with CF3-halides to give oxidative addition products. In the reaction of IrX(CO)(PEt3)2 with CF31, X = Cl, Br, I, and with CF3Br, X = Cl, Br, only the tram addition products are formed.