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Addition of Nitrile Oxides to N-Allylsaccharin.

✍ Scribed by V. Dirnens; S. Belyakov; E. Lukevics


Publisher
John Wiley and Sons
Year
2006
Weight
13 KB
Volume
37
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


Cycloadditions of Nitrile Oxides to Itac
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## Abstract New spiro heterocycles, 1‐oxa‐2,7‐diazaspiro[4.4]non‐2‐ene‐6,8‐diones 3a–c and 8a, c were obtained in the reaction of itaconimides 1a–c with nitrile oxides 2 and 7.

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**The simultaneous migration of two ligands** makes the rearrangement of nitrile oxides __(1)__ to isocyanates __(2)__ one of the most interesting ones in organic chemistry. However, use of the thermal reaction __(1)__ is severely limited by competing dimerization. The rearrangement proceeds in exce