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Cycloadditions of Nitrile Oxides to Itaconimides

✍ Scribed by Svêtlík, Jan ;Liptaj, Tibor ;Hanuš, Vladimír

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
294 KB
Volume
1992
Category
Article
ISSN
0947-3440

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✦ Synopsis

Abstract

New spiro heterocycles, 1‐oxa‐2,7‐diazaspiro[4.4]non‐2‐ene‐6,8‐diones 3a–c and 8a, c were obtained in the reaction of itaconimides 1a–c with nitrile oxides 2 and 7.

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Cycloaddition of Nitrile Oxides to (60)Fullerene. -Addition of nitrile oxides to (60)fullerene gives fullerene-fused isoxazolines (cf. (III)), which can regenerate the (60)fullerene under relatively mild conditions. -(DA