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Addition of inorganic radicals to C60: derivatives of PF4C60

โœ Scribed by J.R. Morton; K.F. Preston

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
286 KB
Volume
255
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The EPR spectrum of PF3(O'B)C6o, a derivative of PFaC6o, is described and discussed. It is concluded that, in the trigonal bipyramidal arrangement of bonds around the phosphorus atom, two of the fluorine atoms occupy axial positions, as might be expected from their electronegativity. The C60 and OrB ligands, and the third fluorine atom, occupy equatorial positions. The enthalpy barrier to Berry pseudo-rotation about the P-C bond is 9.2 + 1.1 kcal/mol.

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