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Addition of hexafluoroacetone to ketenimines

✍ Scribed by Weidler-Kubanek, A. M.; Litt, M. H.

Book ID
127227835
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
402 KB
Volume
33
Category
Article
ISSN
0022-3263

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The reaction of methyl radicals (Me) with hexafluoroacetone (HFA), generated from ditertiary butyl peroxide (dtBP), was studied over the temperature range of 402-433 K and the pressure range of 38-111 torr. The reaction resulted in the following displacement process taking place: where TFA refers t