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Addition of Heteroaromatics to Alkylidenecyclopropanes Catalyzed by Palladium

โœ Scribed by Nakamura, Itaru; Siriwardana, Amal I.; Saito, Shinichi; Yamamoto, Yoshinori


Book ID
127132871
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
77 KB
Volume
67
Category
Article
ISSN
0022-3263

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Palladium-catalyzed addition of ketones
โœ Drexel H Camacho; Itaru Nakamura; Byoung Ho Oh; Shinichi Saito; Yoshinori Yamamo ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 114 KB

Alkylidenecyclopropanes react with ketones under neutral conditions, in the presence of a catalytic amount of Pd(PPh 3 ) 4 to afford the corresponding a-allylated ketone products, in moderate to good yields.