Addition of Grignard Reagents to Aryl Acid Chlorides: An Efficient Synthesis of Aryl Ketones.
β Scribed by Xiao-jun Wang; Li Zhang; Xiufeng Sun; Yibo Xu; Dhileepkumar Krishnamurthy; Chris H. Senanayake
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 25 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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In the presence of anhydrous cerium(III1 chloride, Grignard reagents react with ketones to afford addition products in high yields, even though the substrates are susceptible to abnormal reactions with Grignard reagents alone. ## The reaction of Grignard reagents with carbonyl Sympounds is well-k
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Mono-N-alkyl anilines were obtained in high yields within a short reaction time when various aromatic azides were reacted with alkyl magnesium halides at room temperature.