Addition of Free Radicals to C60
β Scribed by Morton, John R.; Negri, Fabrizia; Preston, Keith F.
- Book ID
- 111694408
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 114 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0001-4842
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract EPR spectra of freeβradical adducts of C~60~ and C~70~ are described and discussed. In the case of addition to C~60~ the prototype radical is HC~60~ or perhaps MuC~60~. The H/Mu hyperfine anomaly in these radicals is explained. The spectra of alkylβC~60~ and fluoroalkylβC~60~ radicals a
The EPR spectrum of PF3(O'B)C6o, a derivative of PFaC6o, is described and discussed. It is concluded that, in the trigonal bipyramidal arrangement of bonds around the phosphorus atom, two of the fluorine atoms occupy axial positions, as might be expected from their electronegativity. The C60 and OrB