Addition of dinitrogen trioxide to norbornene
β Scribed by Scheinbaum, Monte L.
- Book ID
- 126414526
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 273 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
## Abstract Sulfonation of norbornene 1 with the SO~3~βdioxane complex affords the Ξ²βsultone 2, which rearranges at room temperature to the Ξ³βsultone 3. Reaction of 1 with 2 equiv of SO~3~βnitromethane yields the carbyl sulfate 4. Carbocations are __not__ involved in the formation of either the Ξ²βs
To date little has been reported of the generation and addition of bromofluorocarbene to olefins. 4 Accordingly we now report our preliminary results on the basic hydrolysis of dibromofluoromethane as a previous work, norbomene Dibromofluoromethane convenient source of bromofluorocarbene.