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Addition of cyclopentanol to olefins, initiated by tertiary butyl peroxide

✍ Scribed by L. Kh. Freidlin; N. M. Nazarova; D. L. Badalova; G. A. Loginov


Book ID
112419928
Publisher
Springer
Year
1966
Tongue
English
Weight
207 KB
Volume
15
Category
Article
ISSN
1573-9171

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Addition of Trialkyl Methanetricarboxyla
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vinyl-H) and 4.88 T (s) (tert-H) with relative intensities of 3: 1. When the solution is cooled to -54OC the signal from H-7 and H-8 is split reversibly into a doublet plus a singlet, the areas of which indicate a 54:46 equilibrium of endo-cisand exo-cis-dichlorides (boat form), the coalescence temp