Addition of Trialkyl Methanetricarboxylates to 1-Alkenes Initiated by Peroxides

✍ Scribed by Prof. Dr. F. Asinger; Dr. B. Fell; Dipl.-Chem. H. H. Vogel; Dr. H. Meuser

• Publisher: John Wiley and Sons
• Year: 1966
• Tongue: English
• Weight: 131 KB
• Volume: 5
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.196605861

✦ Synopsis

vinyl-H) and 4.88 T (s) (tert-H) with relative intensities of 3: 1. When the solution is cooled to -54OC the signal from H-7 and H-8 is split reversibly into a doublet plus a singlet, the areas of which indicate a 54:46 equilibrium of endo-cisand exo-cis-dichlorides (boat form), the coalescence temperature being -30 "C.