Aldoximes and ketoximes were readily synthesized from aldehydes and hydroxylamine hydrochloride on Al 2 O 3 without solvent under microwave irradiation. At higher irradiation power, aldoximes dehydrated to nitriles and ketoximes rearranged to amides. Aldoximes reacted in a one-pot reaction with Nchl
Addition of 1,3-Benzoxathiole 3-Oxide Anion to Azomethines under Varying Reaction Conditions
✍ Scribed by Salvatore Cabiddu; Enzo Cadoni; Alen Ianni; Gioanna Gelli; Stefana Melis; Angela Maria Bernard; Maria Grazia Cabiddu; Stefania De Montis; Claudia Fattuoni
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 151 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1434-193X
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## Abstract A simple procedure is developed for the synthesis of various propargylamines.
Synthesis of Oximes, Conversion to Nitrile Oxides and Their Subsequent 1,3-Dipolar Cycloaddition Reactions under Microwave Irradiation and Solvent-Free Reaction Conditions. -Aldoximes and ketoximes (II) are readily synthesized from aldehydes and ketones (I) on Al 2 O 3 under microwave irradiation.
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