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Adamantylideneadamantane peroxide, a stable 1,2-dioxetane.

โœ Scribed by J.H. Wieringa; J. Strating; Hans Wynberg; Waldemar Adam


Book ID
108383280
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
163 KB
Volume
13
Category
Article
ISSN
0040-4039

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Synthesis of thermally stable 1,2-dioxet
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Singlet oxygenation of olefins 3 and 6 affords selectively the corresponding 1,2-dioxetanes bearing a phenylethenyl group (1) or a phenylethynyl group (2), which possess marked thermal stability. Treatment of siloxy-substituted analogs lb and 2b with tetrabutylammonium fluoride in DMSO causes the ch