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Adamantyl-β-butyrolactones: synthesis and ring-opening reactions

✍ Scribed by Marija Matković; Krešimir Molčanov; Robert Glaser; Kata Mlinarić-Majerski

Book ID
119375681
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
885 KB
Volume
68
Category
Article
ISSN
0040-4020

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The action of dimercaptoethane on alkyl oxiranes in the presence of benzyltrimethylammonium hydroxide (Triton B) allows, via regiospecific opening reaction, the preparation of the corresponding b,b%-dihydroxy dithioethers in excellent yields.