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Acylation and oxidation of 4-chloro-6-hydroxyaminopyrimidines. Synthesis of 4-chloro-6-nitro(nitroso)pyrimidines

✍ Scribed by O. V. Yagodina; V. F. Sedova; V. P. Mamaev


Publisher
Springer US
Year
1989
Tongue
English
Weight
485 KB
Volume
25
Category
Article
ISSN
0009-3122

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4-Chloro-3′-methylsulfinyl-5(6 or 8)-nit
✍ Maria J. Maślankiewicz 📂 Article 📅 2000 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 362 KB

## Abstract Reaction of 4‐chloro‐3′‐methylthio‐3,4′‐diquinolinyl sulfides **3, 9b, 9c** with a nitrating mixture proceeds via the 3′‐methylthio group monooxidation and yields 3′‐methylsulfinyl diquinolinyl sulfides **4, 5b, 5c**, respectively. Further treatment of **4** with a nitrating mixture fol