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Acyl Derivatives of Aldoses. I. Derivatives of D-glycero-D-gulo-Heptose and D-glycero-L-manno-Heptose

✍ Scribed by Deferrari, Jorge O.; Lederkremer, Rosa Muchnik de

Book ID
126126672
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
398 KB
Volume
27
Category
Article
ISSN
0022-3263

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Three methods for the synthesis of the title compounds starting from benzyl 2,3,4-tri-O-benzyl-cr-D-manno-hexodialdo-1,5-pyranoside (7) have been elaborated. Conversion of 7 into the cyanohydrin followed by reduction to give the amine and then deamination gave a derivative of L-glycero-D-manno-hepto